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Conductivity (electrolytic) : ウィキペディア英語版
Conductivity (electrolytic)
Conductivity (or specific conductance) of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m).
Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems.
In many cases, conductivity is linked directly to the total dissolved solids (T.D.S.). High quality deionized water has a conductivity of about 5.5 μS/m, typical drinking water in the range of 5-50 mS/m, while sea water about 5 S/m〔(【引用サイトリンク】title=Water Conductivity )〕 (i.e., sea water's conductivity is one million times higher than that of deionized water).
Conductivity is traditionally determined by measuring the AC resistance of the solution between two electrodes. Dilute solutions follow Kohlrausch's Laws of concentration dependence and additivity of ionic contributions. Lars Onsager gave a theoretical explanation of Kohlrausch's law by extending Debye–Hückel theory.
==Units==

The SI unit of conductivity is S/m and, unless otherwise qualified, it refers to 25 °C. Often encountered in industry is the traditional unit of μS/cm. 106 μS/cm = 103 mS/cm = 1 S/cm. The values in μS/cm are lower than those in μS/m by a factor of 100 (i.e., 1 μS/cm = 100 μS/m). Occasionally a unit of EC (electrical conductivity) is found on scales of instruments: 1 EC = 1 μS/cm.〔http://www.environment.nsw.gov.au/salinity/basics/units.htm〕 Sometimes encountered is mho (reciprocal of ohm): 1 mho/m = 1 S/m. Historically, mhos antedate Siemens by many decades; good vacuum-tube testers, for instance, gave transconductance readings in micromhos.
The commonly used standard cell has a width of 1 cm, and thus for very pure water in equilibrium with air would have a resistance of about 106 ohm, known as a megohm. Ultra-pure water could achieve 18 megohms or more. Thus in the past, megohm-cm was used, sometimes abbreviated to "megohm". Sometimes, conductivity is given in "microSiemens" (omitting the distance term in the unit). While this is an error, it can often be assumed to be equal to the traditional μS/cm.
The conversion of conductivity to the total dissolved solids depends on the chemical composition of the sample and can vary between 0.54 and 0.96. Typically, the conversion is done assuming that the solid is sodium chloride, i.e., 1 μS/cm is then equivalent to about 0.64 mg of NaCl per kg of water.
Molar conductivity has the SI unit S m2 mol−1. Older publications use the unit Ω−1 cm2 mol−1.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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